Lanthanum-doped reduced graphene oxide modified screen-printed carbon electrode for lactic acid sensing

Retno Supriyanti, Rafi Satria Dwi Awanda, Wahyu Widanarto, Dina Rahmawati, Madya Ardi Wicaksono, Syafrudin Rais Akhdan, Muhammad Alqaaf

Abstract


This study develops a high-performance lactic acid sensor by modifying screen-printed carbon electrodes (SPCEs) with lanthanum-doped reduced graphene oxide (La-rGO). To enable portable and wearable applications, the sensor is integrated into an internet of things (IoT) architecture utilizing a micro-power analog front-end (AFE), an ESP32-C6 controller, and a field-programmable gate array (FPGA) coprocessor for dynamic calibration. Electrochemical characterization demonstrated a high sensitivity of 20.36 µA·mM⁻¹·cm⁻², surpassing unmodified SPCEs. Under optimal conditions, the sensor achieved a limit of detection (LOD) of 13.58 mM and a limit of quantification (LOQ) of 45.28 mM. Furthermore, hardware evaluation showed the FPGA executes temperature compensation with an ultra-low latency of 1.80 µs. A hybrid duty-cycling strategy restricts the average current to 1.85 mA, allowing over 172 hours of continuous operation on a 320 mAh battery. These results demonstrate the hardware-accelerated, IoT-enabled La-rGO/SPCE platform's potential for continuous, non-invasive epidermal sweat analysis.

Keywords


Electrochemical detection; Internet of things; Lactic acid sensor; Reconfigurable hardware field-programmable gate array; Wearable devices

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DOI: http://doi.org/10.11591/ijres.v15.i3.pp671-682

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International Journal of Reconfigurable and Embedded Systems (IJRES)
p-ISSN 2089-4864, e-ISSN 2722-2608
This journal is published by the Institute of Advanced Engineering and Science (IAES) in collaboration with Intelektual Pustaka Media Utama (IPMU).

 

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